2 edition of Elimination of sulfide interference with the colorimetric determination of nitrite found in the catalog.
Elimination of sulfide interference with the colorimetric determination of nitrite
Jenaro A. Acuna
Published
1980
.
Written in
Edition Notes
| Other titles | Colorimetric determination of nitrite. |
| Statement | by Jenaro A. Acuna. |
| The Physical Object | |
|---|---|
| Pagination | [6], 20 leaves, bound : |
| Number of Pages | 20 |
| ID Numbers | |
| Open Library | OL17698548M |
This report documents work at the U.S. Geological Survey (USGS) National Water Quality Laboratory (NWQL) to validate enzymatic reduction, colorimetric determinative methods for nitrate + nitrite in filtered water by automated discrete analysis. In these standard- and low-level methods (USGS I and I), nitrate is reduced to nitrite with nontoxic, soluble nitrate reductase rather. Across many environments, nitrate ($\mbox{NO}_{3}^-$) is an important form of N available for microorganisms and photosynthetic organisms. Accurate $\mbox{NO}_{3}^-$ measurements are important for examining N cycling and retention in terrestrial and aquatic ecosystems, but a common method of $\mbox{NO}_{3}^-$ analysis can underestimate $\mbox{NO}_{3}^-$ concentrations when .
DETERMINATION OF NITRATE-NITRITE NITROGEN BY AUTOMATED COLORIMETRY SCOPE AND APPLICATION This method covers the determination of nitrite singly, or nitrite and nitrate combined in drinking, ground, surface, domestic and industrial wastes. The applicable range is mg/L nitrate-nitrite nitrogen. The range may. Nitrite content of the sample (expressed as mg/L nitrite-N) can be determined by omitting the reduction step and directly reacting the sample with the color dyes. Finally, nitrate-N content can be calculated by subtracting the nitrite content (mg/L nitrite N) from the combined nitrate plus nitrite (mg/L nitrate+nitrite N), to yield the.
The range of linearity for sulfanilic acid-methyl anthranilate couple was found to be µg/ml of nitrite with molar absorptivity be x Lmol-1 cm-1 and sandell’s sensitivity x µg cm The detection limit and quantitation limit of the nitrite determination are found to be μgmL −1 and μgmL −1 respectively. The Water Analysis Handbook (WAH) is the result of more than 65 years of research and method development. With over illustrated, step-by-step instructions, this is your comprehensive source for water analysis procedures.
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Negligible amounts of nitrite occur in plants and drinking water. However, unde r unfavorable conditions nitrite may enter the food ch ain via microb ial reduction of nitrate thus endangering human health.
Application. This semimicro method for determination of nitrite and/ or File Size: KB. The interference of sulfide with the colorimetric determination of nitrite, by the method of Bendschneider and Robinson (), can be eliminated by passing the samples through a cationic exchange resin, Dowex 50W-X8, in the zinc form.
This resin retains sulfide without affecting nitrite and the technique can be applied to automated : Jenaro A. Acuna. Abstract. Graduation date: The interference of sulfide with the colorimetric determination of\ud nitrite, by the method of Bendschneider and Robinson (), can be\ud eliminated by passing the samples through a cationic exchange resin,\ud Dowex 50W-X8, in the zinc form.
and continues indefinitely. Iodine originating from the nitrite-iodine reaction interferes in the iodometric titration of sulfite.
A method for the determination of sulfite in thin juice that con tains nitrite has been developed. T he method is based on elimination of nitrite in the thin juice with hydrazine sulfate, addition of sample to.
Elimination of sulphite interference in the spectrophotometric determination of nitrite R. Lew, Analyst, DOI: /AN To follow the progress of nitrogen elimination, ammonium, nitrite and nitrate concentrations were determined at all stages of the process.
While the nitrite and nitrate concentrations were measured by conventional colorimetric methods, No interference of the complex sample matrix was found in ammonium determination.
Colorimetric Determination of Nitrate Plus Nitrite in Water by Enzymatic Reduction, Automated Discrete Analyzer Methods By Charles J. Patton and Jennifer R. Kryskalla Chapter 8 Section B, Methods of the National Water Quality Laboratory Book 5, Laboratory Analysis Techniques and Methods 5–B8 U.S.
Department of the Interior U.S. Geological Survey. Distilled water free of nitrite and nitrate is to be used in preparation of all reagents and standards. Sodium chloride solution (30%): Dissolve g NaCl in distilled water and dilute to 1 liter.
Sulfuric acid solution: Carefully add mL conc. H 2SO 4 to ml distilled water. To check the reproducibility and the interference of sulfide on nitrite detection, two working protocols related to anion addition were proposed. The first representing the detection of nitrite in the presence of sulfide consisted of adding a sulfide concentration up to desired maximum level followed by adding nitrite concentrations (Figure 3 a).
4 TABLE OF CONTENTS, continued NITRATE, High Range, Test ‘N Tube, Chromotropic Acid Method. NITRITE, High Range, Ferrous Sulfate Method. Note: If sulfide removal cannot be done at time of sample collection, samples may be sent unpreserved to the laboratory for sulfide treatment within 24 hours of collection.
iii. Lead acetate strip cannot detect sulfide at ppb levels. Amperometric detection is especially sensitive to sulfide interference. 5. Sodium sulfide determination before (0) and after (O) treatment with H ( Umol/ml) and Na2S0, ( Amol/ml).
SYLVESTER ET AL. sodium thiosulfate can produce a positive interference with the potentiometric determination of cyanide. Colorimetric, Automated, Ascorbic Acid: 6: P F: P F “Waters Test Method for Determination of Nitrite/Nitrate in Water Using Single Column Ion Chromatography,” August, Test samples using a more sensitive sulfide method to determine if a sulfide interference is present, and treat samples accordingly.
Colorimetric Determination of Nitrate and Nitrite in Milk and Milk Powders - Use of Vanadium (III) Reduction. it does not cause interference in the presence of iron. Colman (B) University of California, Santa Barbara, CA, USA e-mail: [email protected] Keywords Iron interference Colorimetric analysis Nitrate Nitrite Introduction Nitrate (NO− 3)is an important source of N for ter-restrial and aquatic ecosystems, including ground.
• The proposed Method Update Rule (MUR) approved a new method for the analysis of nitrate, nitrite, and nitrate-nitrite, Method N, Nitrat e Reductase Nitrate-Nitrogen Analysis. Particularly, a number of PADs and microfluidic PADs (µ-PADs) have been reported in the literature for the non-instrumental colorimetric determination of nitrite [15] [16][17][18][19][20][21][ Determination of the phosphorus content of lipids.
Journal of the American Oil Chemists' Society31 (4), DOI: /BF Burakham et al. developed a novel spectrophotometric reaction system for the determination of nitrite as well as nitrate in water samples based on the nitrosation reaction between nitrite ion and phloroglucinol (1,3,5-trihydroxybenzene).
The system was applied to a flow-injection analysis and up to 20 samples can be analyzed per hour with a. Abstract A new method was developed for the determination of nitrate based on a soluble powder containing zinc and a bluish diazotizing solution. In this procedure about 10% of the nitrate content of the sample is converted to nitrite, but the intensity of the color developed is proportional to the nitrate content.
The color changes from blue through green to yellow. interferants. As a general guide, 1 mL of silver sulfate will eliminate chloride interference in a mL sample containing 35 mg/L of Cl G.
1 mL of sulfamic acid solution will eliminate nitrite interference in a mL sample containing 95 mg/L of NO 2 G. Temperature changes affect electrode potentials (Reference 2).
Therefore.value obtained for Nitrite is then subtracted from the nitrate + Nitrite value to determine the true value for nitrate. The method has several advantages over USEPA methods nitrate Hydrazine Reduction, and nitrate Cadmium Reduction, including elimination of hazardous waste and hydrazine and cadmium exposure.
The. 6 Excerpt from the U.S. EPA Methods Update Rule, pp “EPA proposes to add the USGS Methods I and I titled “Colorimetric Determination of Nitrate plus Nitrite in Water by Enzymatic Reduction, Automated.
